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The gas constant is the constant of proportionality that relates the energy scale in physics to the temperature scale and the scale used for amount of substance. Thus, the value of the gas constant ultimately derives from historical decisions and accidents in the setting of units of energy, temperature and amount of substance.
The enthalpy of vaporization is a function of the pressure and temperature at which the transformation ( vaporization or evaporation) takes place. The enthalpy of vaporization is often quoted for the normal boiling temperature of the substance. Although tabulated values are usually corrected to 298 K, that correction is often smaller than the ...
The specific heat of the human body calculated from the measured values of individual tissues is 2.98 kJ · kg−1 · °C−1. This is 17% lower than the earlier wider used one based on non measured values of 3.47 kJ · kg−1· °C−1. The contribution of the muscle to the specific heat of the body is approximately 47%, and the contribution ...
The Clausius–Clapeyron relation describes a Phase transition in a closed system composed of two contiguous phases, condensed matter and ideal gas, of a single substance, in mutual thermodynamic equilibrium, at constant temperature and pressure. Therefore, [ 7]: 508. Using the appropriate Maxwell relation gives [ 7]: 508 where is the pressure.
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. [1] The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property. The corresponding intensive property is the specific heat capacity, found ...
Arrhenius originally considered A to be a temperature-independent constant for each chemical reaction. [6] However more recent treatments include some temperature dependence – see § Modified Arrhenius equation below. E a is the molar activation energy for the reaction, R is the universal gas constant. [1] [2] [4]
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer