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Lipid peroxidation, or lipid oxidation, is a complex chemical process that leads to oxidative degradation of lipids, [1] resulting in the formation of peroxide and hydroperoxide derivatives. [2] It occurs when free radicals, specifically reactive oxygen species (ROS), interact with lipids within cell membranes, typically polyunsaturated fatty ...
Oxidative stress reflects an imbalance between the systemic manifestation of reactive oxygen species and a biological system's ability to readily detoxify the reactive intermediates or to repair the resulting damage. [ 1] Disturbances in the normal redox state of cells can cause toxic effects through the production of peroxides and free ...
The hydroxyl radical, •HO, is the neutral form of the hydroxide ion (HO – ). Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry. Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction ...
The peroxide value is defined as the amount of peroxide oxygen per 1 kilogram of fat or oil. Traditionally this was expressed in units of milliequivalents, although in SI units the appropriate option would be in millimoles per kilogram (N.B. 1 milliequivalents = 0.5 millimole; because 1 mEq of O2 =1 mmol/2=0.5 mmol of O2, where 2 is valence).
High-test peroxide ( HTP) is a highly concentrated (85 to 98%) solution of hydrogen peroxide, with the remainder consisting predominantly of water. In contact with a catalyst, it decomposes into a high-temperature mixture of steam and oxygen, with no remaining liquid water. It was used as a propellant of HTP rockets and torpedoes, and has been ...
A persulfate (sometimes known as peroxysulfate or peroxodisulfate) [ 1] is a compound containing the anions SO2−. 5 or S. 2O2−. 8. [ 2] The anion SO2−. 5 contains one peroxide group per sulfur center, whereas in S. 2O2−. 8, the peroxide group bridges the sulfur atoms. In both cases, sulfur adopts the normal tetrahedral geometry typical ...
A peroxy acid (often spelled as one word, peroxyacid, and sometimes called peracid) is an acid which contains an acidic –OOH group. The two main classes are those derived from conventional mineral acids, especially sulfuric acid, and the peroxy derivatives of organic carboxylic acids. They are generally strong oxidizers .
The self-accelerating decomposition temperature ( SADT) is the lowest temperature at which an organic peroxide in a typical vessel or shipping package will undergo a self-accelerating decomposition within one week. [1] The SADT is the point at which the heat evolution from the decomposition reaction and the heat removal rate from the package of ...