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6. Linux - Wikipedia

   en.wikipedia.org/wiki/Linux

   Linux (/ ˈ l ɪ n ʊ k s /, LIN-uuks) [11] is a generic name for a family of open-source Unix-like operating systems based on the Linux kernel, [12] an operating system kernel first released on September 17, 1991, by Linus Torvalds.

7. Tadalafil - Wikipedia

   en.wikipedia.org/wiki/Tadalafil

   Tadalafil is an annulated 2,5-diketopiperazine. [25] It is also a 1,2,3,4-tetrahydro-β-carboline. Tadalafil can be synthesized starting from (D)-tryptophan methyl ester and piperonal via a Pictet–Spengler reaction. This is followed by condensations with chloroacetyl chloride and methylamine to complete the diketopiperazine ring: [26]